Is Zakah due on the orphan`s money?
Yes, Zakah is due on the money of the orphan.
I missed fasting 30 days of the obligatory fast within the last 6 years and 20 days. How do I fast? And what should I do?
Missed fasting days must be made up, and it is permissible to make them up on non-consecutive days, as continuity is not required for making up missed fasts. Additionally, expiation (Fidya) must be given: feeding one needy person for each day if the makeup is delayed for one year. If the delay extends to two years, Fidya must be given to two needy people per day, and so on. And Allah Knows Best.
Is it permissible for a woman to adorn herself with kohl (eyeliner) and go out wearing it?
Kohl is a form of adornment, and it is forbidden for a woman to display her adornment to anyone other than her husband or a Mahram. And Allah Knows Best.
Is it permissible for one to masturbate in order not to commit fornication?
This is called committing the milder of the two evils such as eating a carcass in fear of death, and this happens when committing fornication is very likely to occur.