Is it permissible for the guardian to give Sadaqa (voluntary charity) from the money of the orphans?
It is impermissible for the guardian to donate from the money of the orphans because he is entrusted with the safekeeping of that money, and is prohibited from donating it.
Does sacrificing one sheep avail for the entire household?
Praise be to Allah, and peace and blessings be upon our master, the Messenger of Allah.
In Islamic jurisprudence, the sacrifice (Udhiyah) is considered a Communal Sunnah (Sunnah Kifayah) for the members of a single household who share the same financial support.
If one member of the household performs the sacrifice—even if they are not the primary breadwinner, such as the wife or one of the children—the religious request is fulfilled on behalf of the entire household. This is similar to the Funeral Prayer (Salat al-Janazah), where the obligation is dropped for the community if some perform it.
While the communal request is satisfied by one person's action, the specific spiritual reward (Thawab) for the act of worship belongs only to the person who sacrificed, unless that individual explicitly intends to include the other family members in the reward.
A single sacrifice also avails for a man who is married to more than one wife. And Allah the Almighty knows best.
Is the prayer of a woman who is led by an Imam via T.V. permissible?
All perfect praise be to Allah, The Lord of The Worlds, and may His Peace and Blessings be upon our Prophet Muhammad and upon all of his family and companions. Amongst the conditions for the validity of prayer is that both the Imam and those led by him must be in the same place. Thus, the prayer of the person who is being led by a televised Imam is invalid unless he/she was with him in the same mosque. And Allah Knows Best.
Is it permissible for a woman to shake hands with her brother-in-law?
It is forbidden for the woman to shake hands with her brother-in-law because he isn`t a Mahram (unmarriageable) of hers.