Is it permissible for a person who has to make up for missed fasts to fast six days of Shawal(the month directly after Ramdhaan) before making up for the missed fasts ?
Yes, it is permissible for him/her to do so, but it is better that they make up for missed fasts first.
What is the ruling on not fulfilling a vow?
A vow is a commitment towards Allah, The Almighty, and so, it should be observed as much as possible, and it is impermissible to take it lightly. Allah, The Exalted, says –in commending the believers-: “(Because) they perform the vow and fear a day whereof the evil is wide-spreading,”{Al-Insan/7}.
Is it permissible for a woman to uncover her face while performing Umrah(minor Hajj)?
The woman who is in a state of Ihram(ritual consecration) should uncover her face and hands, but it is permissible for her to let her head-covering garment drape from her head down over her face when non-Mahram (i.e., marriageable) men pass by her.
Is it permissible for the guardian to give Sadaqa( voluntary charity )from the money of the orphans?
It is impermissible for the guardian to donate from the money of the orphans because he is entrusted with the safekeeping of that money, and is prohibited from donating it.