Does the deceased hear the supplications or recitations of those visiting his/her grave? And does making constant supplications for the deceased who didn`t adhere to performing the prescribed prayers ameliorate his/her affliction?
Praise be to Allah the Lord of the Worlds.
In principle, the dead hear the living since it has been rigorously authenticated that the Prophet (peace and blessings be upon him) ordered the bodies of the idolaters slain in the Battle of Badr to be buried. He then approached them and called them one by one and said, “Have you found what your Lord promised to be true for we have found what our Lord promised us to be true.” ‘Umar asked him, “O messenger of God! Why do you speak to lifeless bodies?” The Prophet (peace and blessings be upon him) replied, “By the One Who has sent me with the truth! You do not hear my words better than they do except that they cannot respond.”{Related by Bukhari & Muslim}.
However, not all the deceased are in the same situation because Allah the Almighty says, "Before them is a Partition till the Day they are raised up."{Al-Mu`minun, 100}. Moreover, supplication reaches the deceased. And Allah knows best.
What is the ruling on performing voluntary prayers during official working hours?
There is no harm if there was break time during official working hours, but if not then it is impermissible. And Allah Knows Best.
Is it permissible for a woman to pluck her eyebrows, or to shave them and have a tattoo in their place?
It is forbidden for a woman to pluck her eyebrows, or to shave them and have a tattoo in their place since this is called (Nums), and the Prophet(PBUH) has cursed those who do it.
Is it permissible for the big brother to force his sisters to wear Hijjab(Islamic wear) if their father didn`t do his part in this regard ?
The father`s attention should be drawn gently and politely, and the sisters should also be reminded with good words since Allah, The Almighty, says: “O ye who believe! Save yourselves and your families from a Fire whose fuel is Men and Stones.”{Al-Tahreem/6}.